What is this? 037

What is this?

A diagram of organic compounds with rings

What elements do N, H, O, S, Si, and P represent?

nitrogen, hydrogen, oxygen, sulfur, silicon, and phosphorus

What other elements are implied?

carbon is implied by the junction between two line segments

hydrogen is implied anywhere there is a carbon with less than 4 bonds.

What do the double lines represent?

double bonds

How many carbons are in pyridine?

5 carbons

How many hydrogens are in pyrrole?

5; 1 shown and 4 implied

Why are hydrogens shown in pyrrole and silabenzene?

In diagrams of organic molecules, hydrogens are shown unless they are attached to carbons

What do the numbers represent?

These label the atoms in the ring, starting with the non-carbon atom. These numbers are used to name compounds derived from these molecules with an atom substituting for one of the hydrogens.

For instance, this is 2-chloropyridine:

This is 3-chloropyridine:

Why don’t the numbers go all the way around?

Symmetry

Substituting an element at what would be the carbon in the 6th position of phosphorine would be the same as substituting in the 2nd position. 6-chloropyridine would be the same as 2-chloropyridine.

However, once one substitution has been made, it breaks the symmetry and adding a second substitution might require numbering the other atoms up to 6.

This is 2,6-dichloropyridine:

Goals of this image:
  • Basic chemistry
    • Recognizing symbols of elements
  • Interpreting diagrams of organic compounds
    • Implied carbons and hydrogens
    • Single and double bonds
    • Numbering system

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